Even in vCloud Director, a vApp construct is still bounded to a single vCenter but of course that vApp can be deployed across multiple vCenter Servers using the transfer store. One cool feature that I recently learned about is something called multi-machine in the new vCloud Automation Center which allows you to constructu a "vApp" like construct but the VMs are allowed to span across vSphere, vCloud, physical/virtual, public cloud/private cloud. It's a pretty nifty idea and you can read more about it in the What's New doc http://www.vmware.com/resources/techresources/10340
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